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Synthesis of two useful, enantiomerically pure derivatives of (S)-4-hydroxy-2-cyclohexenone

✍ Scribed by Audia, James E.; Boisvert, Louise; Patten, Arthur D.; Villalobos, Anabella; Danishefsky, Samuel J.

Book ID
126854204
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
436 KB
Volume
54
Category
Article
ISSN
0022-3263

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Asymmetric synthesis of (R) and (S)-4-hy
Asymmetric synthesis of (R) and (S)-4-hydroxy-2-cyclohexenone and derivatives
✍ M Carmen CarreΓ±o; JosΓ© L GarcΓ­a Ruano; Mercedes Garrido; M Pilar Ruiza; Guy Soll πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 293 KB

The arymmeti syntheses of both enantiomers of 4and O-benql derivatives are reported z4 DIBAL and ZnCl2/DI aTmy-2qciohewnone and their 0-acetyl L stemaelective reducrionr of the ketosulfaides resulting in the sul'nylation of Al-cyciohexanedione ethylene monoketai, are the key steps in these syntheses