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Asymmetric synthesis of (R) and (S)-4-hydroxy-2-cyclohexenone and derivatives

✍ Scribed by M Carmen Carreño; José L García Ruano; Mercedes Garrido; M Pilar Ruiza; Guy Solladié

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 293 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)97138-7

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✦ Synopsis

The arymmeti syntheses of both enantiomers of 4and O-benql derivatives are reported z4 DIBAL and ZnCl2/DI aTmy-2qciohewnone and their 0-acetyl L stemaelective reducrionr of the ketosulfaides resulting in the sul'nylation of Al-cyciohexanedione ethylene monoketai, are the key steps in these syntheses.

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