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Efficient synthesis of enantiomerically pure 5,5-Dimethyl-4-hydroxy-2-cyclopentenone

✍ Scribed by Hiroaki Miyaoka; Shoichi Sagawa; Hiroto Nagaoka; Yasuji Yamada


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
461 KB
Volume
6
Category
Article
ISSN
0957-4166

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Photoaddition Reactions of 5-Fluoro-4,4-
✍ Giao Vo Thi; Paul Margaretha 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 456 KB

## Abstract The photoaddition of 5‐fluoro‐4,4‐dimethyl‐2‐cyclopentenone (**4**) to 2,3‐dimethyl‐2‐butene leads specifically (in cyclohexane) and selectively (in acetonitrile) to the formation of the oxetanes **16**. The title compound is compared in its behaviour to the analogous 6‐fluoro‐4,4‐dimet