Tricarbonyl-η 6 -[(2-thiophenyl
Synthesis of tricarbonyl η6- and η5-[(3-thiophenyl)organo]chromium and -manganese complexes
✍ Scribed by Damien Prim; José Giner Planas; Audrey Auffrant; Françoise Rose-Munch; Eric Rose; Jacqueline Vaissermann
- Book ID
- 108187755
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 370 KB
- Volume
- 688
- Category
- Article
- ISSN
- 0022-328X
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📜 SIMILAR VOLUMES
## Abstract The Cr(CO)~3~‐complexed η6‐phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro‐ or phosphoryl allenyl substituted η6‐phenyl complexes 4 and 6, respectively. In the X‐ray crystal structure of the novel org
Addition of a nucleophile to an (η 6 -arene)tricarbonylchromium or a tricarbonyl(η 5 -cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves