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Synthesis and characterization of tricarbonyl[η6-(phenylethynyl)arene]chromium complexes: crystal structure of tricarbonyl[η6-(3-phenylethynyl)anisole]chromium

✍ Scribed by Fung-E Hong; Shih-Chun Lo; Ming-Woei Liou; Yuan-Terng Chang; Chu-Chieh Lin

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
539 KB
Volume
506
Category
Article
ISSN
0022-328X

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## Abstract The Cr(CO)~3~‐complexed η6‐phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro‐ or phosphoryl allenyl substituted η6‐phenyl complexes 4 and 6, respectively. In the X‐ray crystal structure of the novel org