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cine and tele Nucleophilic Substitutions in (η6-Arene)tricarbonylchromium and Tricarbonyl(η5-cyclohexadienyl)manganese Complexes

✍ Scribed by Françoise Rose-Munch; Eric Rose

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
351 KB
Volume
2002
Category
Article
ISSN
1434-1948

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✦ Synopsis

Addition of a nucleophile to an (η 6 -arene)tricarbonylchromium or a tricarbonyl(η 5 -cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves ad- [a]

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