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ChemInform Abstract: (η6-Arene)tricarbonylchromium and (η5-Cyclohexadienyl)tricarbonylmanganese Complexes: Indirect Nucleophilic Substitutions

✍ Scribed by Francoise Rose-Munch; Vanessa Gagliardini; Christophe Renard; Eric Rose

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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cine and tele Nucleophilic Substitutions
cine and tele Nucleophilic Substitutions in (η6-Arene)tricarbonylchromium and Tricarbonyl(η5-cyclohexadienyl)manganese Complexes
✍ Françoise Rose-Munch; Eric Rose 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 351 KB

Addition of a nucleophile to an (η 6 -arene)tricarbonylchromium or a tricarbonyl(η 5 -cyclohexadienyl)manganese complex substituted with a leaving group X (X = F, Cl, OMe, OPh, NR 2 ) affords (after treatment with acid) new complexes with the same η 6 or η 5 hapticity. The overall reaction involves