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Synthesis of triazole- and pyridine-bridged porphyrin–chlorin and porphyrin dimers

✍ Scribed by Afaf R. Genady; Detlef Gabel

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
114 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

The synthesis of 4-amino-1,2,4-triazole linked porphyrin-chlorin dimer and porphyrin dimer is described. New cationic porphyrin dimers were synthesized via the alkylation of the nitrogen atoms of 4,4%-bipyridine and 1,2-di-(4-pyridyl)ethene by meso-monobromomethylporphyrin. These cationic bisporphyrins can interact with DNA and have the ability to cleave it.

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