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Synthesis of Trifluoromethyl-Porphyrins and -Chlorins

✍ Scribed by Hitoshi Tamiaki; Yasushi Nagata; Seiichi Tsudzuki


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
217 KB
Volume
1999
Category
Article
ISSN
1434-193X

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✦ Synopsis


Reaction of zinc 5,15-bis(3,5-di-tert-butylphenyl)porphyrin and 10,20-di-CF 3 -porphyrins as the minor products. The direct trifluoromethylation is effective for preparation of with S-(trifluoromethyl)-3,7-dinitrobenzothiophene trifluoromethanesulfonate in tetrahydrofuran gave the 10-tri-longer-wavelength absorbing meso-trifluoromethylated porphyrins and chlorins. fluoromethylated compound as the major product and 2-CF 3 -


📜 SIMILAR VOLUMES


ChemInform Abstract: Porphyrins. Part 37
✍ D. V. Yashunsky; D. P. Arnold; G. V. Ponomarev 📂 Article 📅 2000 🏛 John Wiley and Sons ⚖ 24 KB

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