Porphyrin Dimers Bridged by an Electrochemically Switchable Unit
β Scribed by Chi-Lun Mai; Yi-Lin Huang; Gene-Hsiang Lee; Shie-Ming Peng; Chen-Yu Yeh
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 259 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
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π SIMILAR VOLUMES
La@C 82 is recognized by an isophthaloyl-bridged porphyrin dimer forming a stable 1:1 supramolecular complex with an association constant K assoc = (67.3 Β± 3.2) Γ 10 3 M Γ1 .
A new linear switchable diporphyrin array has been the host-guest complexes promotes a change of the geometry of the system toward a topology in which the two synthesized in good yield by a Williamson coupling of 5-(4Πhydroxyphenyl)-10,15,20-triphenylporphyrin with tetraethyl-tetrapyrrolic macrocycl
Reaction of various ct-unsubstituted pyrrole derivatives with trimethyl(porphyrinylmethyl)ammonium iodides (generated in situ from the corresponding meso-dimethylaminomethylporphyrins and iodomethane) afforded a number of symmetrical and unsymmetrical porphyrinylmethylpyrrole adducts, including dime