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Chemistry of dimethylaminomethylporphyrins. 2. Porphyrin dimers linked by pyrrolylmethylene units

✍ Scribed by Dmitry V. Yashunsky; Gelli V. Ponomarev; Dennis P. Arnold

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 183 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(96)02227-7

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✦ Synopsis

Reaction of various ct-unsubstituted pyrrole derivatives with trimethyl(porphyrinylmethyl)ammonium iodides (generated in situ from the corresponding meso-dimethylaminomethylporphyrins and iodomethane) afforded a number of symmetrical and unsymmetrical porphyrinylmethylpyrrole adducts, including dimers linked by one and two pyrrolylmethylene units. The NMR spectra of the monopyrrolelinked dimers indicate a preference for a face-to-face conformation.

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