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Synthesis of transition-metal based nonlinear optical organometallic fullerene derivatives C60M2 (M = Pd, Pt)

✍ Scribed by Yanghui Lin; Ruifang Cai; Yu Chen; Zu-En Huang; Yinghua Zhou; Guohong Ma

Book ID
110239225
Publisher
Springer
Year
1999
Tongue
English
Weight
48 KB
Volume
18
Category
Article
ISSN
0261-8028

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Synthesis, Characterization and Electrochemical Properties of Optically Active [60]Fullerene Organotransition Metal Complexes mer-[(Ξ·2-C60)M(CO)3{(βˆ’)-DIOP}] (M = Mo, W), mer-[(Ξ·2-C60)M(CO)3{(+)-DIOP}] (M = Mo, W) and [(Ξ·2-C60)M{(βˆ’)-DIOP}] (M = Pd, Pt) βˆ’ Crystal Structure of [(Ξ·2-C60)Pt{(βˆ’)-DIOP}]
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## Abstract This paper reports on several new optically active organometallic [60]fullerene complexes that contain a chiral (+)‐DIOP or (βˆ’)‐DIOP ligand [DIOP = 2,3‐__O__,__Oβ€²__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphanyl)butane]. The Mo/W complexes __mer__‐[(Ξ·^2^‐C~60~)M(CO)~3~{(βˆ’)‐DIOP