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Synthesis of the sodium salts of methyl 2-O-α-l-fucopyranosyl-α-l-fucopyranoside 3- and 4-sulfate

✍ Scribed by Rakesh K. Jain; Khushi L. Matta

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
609 KB
Volume
208
Category
Article
ISSN
0008-6215

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✦ Synopsis

Synthesis of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate was accomplished through the use of a key glycosyl donor, methyl 2,3,4-tri-O-benzyl-1-thio-beta-L-fucopyranoside, with methyl 2,3-O-isopropylidene-alpha-L-fucopyranoside and methyl 4-O-acetyl-3-O-benzyl-alpha-fucopyranoside as acceptors.

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