In a previous papeti in this series, we described the synthesis of L-fucosyldisaccharides having sulfate groups at C-3 or C-4. Such r\_-fucosyl-oligosaccharides occur naturally as a part of the structure of fucoidan, a sulfated L-fucose polysaccharide, know to possess anticoagulant acticity 3,4 This
Synthesis of p-nitrophenyl 2-O-α- and -β-l-fucopyranosyl-β-d-fucopyranoside
✍ Scribed by Khushi L. Matta; Surjit S. Rana; Conrad F. Piskorz; Joseph J. Barlow
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 652 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0008-6215
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📜 SIMILAR VOLUMES
Condensation of benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-a-D-galactopyranoside with 2,3,4-tri-o-acetyl-a-D-fucopyranosyl bromide in 1: 1 nitromethane-benzene, in the presence of powdered mercuric cyanide, afforded benzyl 2-acetamido-4,6-O-benzylidene-2-deoxy-3-0-(2,3,4-tri-O-acetyl-P-D-fucopyran
Synthesis of methyl 2-O-alpha-L-fucopyranosyl-alpha-L-fucopyranoside 3- and 4-sulfate was accomplished through the use of a key glycosyl donor, methyl 2,3,4-tri-O-benzyl-1-thio-beta-L-fucopyranoside, with methyl 2,3-O-isopropylidene-alpha-L-fucopyranoside and methyl 4-O-acetyl-3-O-benzyl-alpha-fucop