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Synthesis of methyl 2,4-di-O-methyl-3-O-(2-O-methyl-α-l-rhamnopyranosyl)-α-l-rhamnopyranoside and methyl 2,4-di-O-methyl-3-O-[2-O-methyl-3-O-(2-O-methyl-α-l-fucopyranosyl)-α-l-rhamnopyranosyl]-α-l- rhamnopyranoside: di- and tri-saccharide segments of a phenolic glycolipid of Mycobacterium kansasii

✍ Scribed by Mukund K. Gurjar; K.Revathi Reddy

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
443 KB
Volume
226
Category
Article
ISSN
0008-6215

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✦ Synopsis

Syntheses of the title glycosides are described. The critical O-glycosylations were carried out in the presence of boron trifluoride etherate with a high degree of alpha-selectivity.

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