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Synthesis of allyl and benzyl 4-O-(3,6-di-O-methyl-β-d-glucopyranosyl)-2,3-di-O-methyl-α-l-rhamnopyranoside

✍ Scribed by Jose R. Mariño-Albernas; Vicente Verez-Bencomo; Leandro Gonzalez; Carlos S. Perez

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
803 KB
Volume
165
Category
Article
ISSN
0008-6215

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✦ Synopsis

Condensation of 2,4-di-O-acetyl-3,6-di-O-methyl-a-~glucopyranosyl bromide with either ally1 or benxyl2,4-di-0-methyl-cu+rhamnopyranoside in the presence of mercuric cyanide, followed by 0-deacetylation, gave the title oligosaccharides in excellent yields.

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