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Synthesis of the Lipophilic Antifolate Piritrexim via a Palladium(0)-Catalyzed Cross-Coupling Reaction

โœ Scribed by Chan, David C. M.; Rosowsky, Andre

Book ID
124068869
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
119 KB
Volume
70
Category
Article
ISSN
0022-3263

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Synthesis of chiral N-aryl pyrrolidinone
Synthesis of chiral N-aryl pyrrolidinones via a palladium-catalyzed cross-coupling reaction
โœ R.Greg Browning; Hossen Mahmud; Vivek Badarinarayana; Carl J Lovely ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 62 KB

The direct synthesis of non-racemic N-aryl pyrrolidinones through the application of the Buchwald/Hartwig aryl amination reaction is reported. These reactions proceed in generally good yield, with a variety of electron deficient aryl bromides and with retention of stereochemical purity.