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Synthesis of the indoloazocine derivatives from a chiral indol amide-stabilized sulfur ylide

✍ Scribed by Juárez-Calderón, Maira; Aparicio, David M.; Gnecco, Dino; Juárez, Jorge R.; Orea, Laura; Mendoza, Angel; Sartillo-Piscil, Fernando; del Olmo, Esther; Terán, Joel L.


Book ID
120189822
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
804 KB
Volume
54
Category
Article
ISSN
0040-4039

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Synthesis of Chiral Epoxides from Aldehydes Using Sulfur Ylide Derived from Reduced Product of Baker's Yeast Reduction. -Baker's yeast reduction of the cyclic β-keto esters (I) provides an enantiomerically pure β-hydroxy ester (II) in the presence of sulfur compounds as additives. A sulfur ylide der