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Synthesis of the Four-Membered Metallacycle [Cp2Ti(AsPh)3] via the in situ Reduction of [Cp2 TiCl2]

โœ Scribed by Paul Mercando; Anthony-Joseph DiMaio; Prof. Arnold L. Rheingold


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
240 KB
Volume
26
Category
Article
ISSN
0044-8249

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Reductive Cleavage of the Carbon-sulfur
โœ Jia Xue-Shun; Zhang Yong-Min ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 28 KB ๐Ÿ‘ 1 views

A mild and rapid method was found for the reductive cleavage of the carbon-sulfur bond in the alkylthiocyanates by samarium/Cp 2 TiCl 2 system to give the corresponding dialkyl disulfides in moderate to good yields.