Synthesis of the first 2,2'-biphosphinine. X-ray crystal structure analysis of its tetracarbonylchromium complex
β Scribed by Le Floch, Pascal; Carmichael, Duncan; Ricard, Louis; Mathey, Francois
- Book ID
- 127362275
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 407 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0002-7863
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]pyridines (THPP) upon the reaction with DMAD in acetonitrile or DMSO at rt underwent ring expansion, affording tetrahydropyrrolo[2,3-d]azocines; these latter compounds have not previously been reported in the literature. The crystal structure and conformation of these derivatives was established by
The synthesis and X-ray crystal structure determination of a novel metal-terphenyl derivative, namely DmpAuPPh 3 (1), is reported (Dmp = 2,6-dimesitylphenyl). Complex 1 is synthesized by the reaction of one equivalent of DmpLi with one equivalent of Ph 3 PAuCl in tetrahydrofuran at room temperature