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4,5-Dimethyl-2-(2-pyridyl)phosphorin as a chelating ligand. Synthesis and x-ray crystal structure analysis of (4,5-dimethyl-2-(2-pyridyl)phosphorin)tetracarbonylchromium

โœ Scribed by Breque, Anne; Santini, Catherine C.; Mathey, Francois; Fischer, Jean; Mitschler, Andre


Book ID
120425439
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
675 KB
Volume
23
Category
Article
ISSN
0020-1669

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โœ Robert B. Palmer; Niels H. Andersen ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 242 KB

We report the synthesis and X-ray crystal structure of 1,4-dihydro-2,6-dimethyl-4-(2'isopropylphenyl)-3,5-pyridine-dicarboxylic acid dimethyl ester (4), an analogue of the 1,4dihydropyridine calcium channel antagonist, nifedipine. Solution state NOE data indicate the presence of both rotameric forms