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Synthesis of the enantiopure C15–C26 segment of phorboxazole A and B

✍ Scribed by Peter Wolbers; Andrea M. Misske; H. Martin R.%Hoffinann


Book ID
104261586
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
209 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


Two approaches towards an enantiopure C15-C26 segment of the phorboxazoles starting from the corresponding C20-C26 aldehyde are presented. A variety of functionalized oxazoles have been synthesized via the rhodium(lI) acetate catalyzed cycloaddition of dimethyl diazomalonate to substituted nitriles.


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ChemInform Abstract: Structure—Activity
✍ P. Wolbers; H. M. R. Hoffmann; F. Sasse 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

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