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Synthesis of the C(17)–C(27) fragment of the 20-deoxybryostatins

✍ Scribed by Pedro Almendros; Alastair Rae; Eric J. Thomas

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 78 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01697-x

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✦ Synopsis

A synthesis of the C(17)-C( 27) fragment of the 20-deoxybryostatins is described in which the key step is a palladium(0) catalysed coupling of a tributyltin enolate with a vinylic bromide.

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