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Synthesis of the C 1 −C 12 Fragment of the Tedanolides. Aldol−Non-Aldol Aldol Approach

✍ Scribed by Jung, Michael E.; Yoo, Dongwon

Book ID
127057838
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
100 KB
Volume
9
Category
Article
ISSN
1523-7060

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Use of the non-aldol aldol process in th
Use of the non-aldol aldol process in the synthesis of the C1–C11 fragment of the tedanolides: use of lactol ethers in place of tetrahydrofurans
✍ Michael E Jung; Christopher P Lee 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 107 KB

The use of a lactol methyl ether 23 in place of the simple tetrahydrofuran 11 allows for the high yielding non-aldol aldol process to occur without concomitant tetrahydropyran formation (cf. 13) to give the desired product 24 in good yield.