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Synthesis of the barbaralone nucleus via photocyclization of an alkynyl tropone

✍ Scribed by Ken S Feldman; John H Come; Glenn J Fegley; Bradley D Smith; M Parvez

Book ID
104227427
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
229 KB
Volume
28
Category
Article
ISSN
0040-4039

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✍ Hiroyuki Miyano; Makoto Nitta πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 255 KB

## 2-Halocycloheptadienone enolates, 7 which were generated by the reaction of 2-halotropones with hydride, Grignard, and organolithium reagents, reacted with cationic electrophiles including tropylium ion to give 2-substituted tropone derivatives.