✦ LIBER ✦

Umpolung of tropone: The synthesis of novel 2-substituted tropones via 2-halocycloheptadienone enolates

✍ Scribed by Hiroyuki Miyano; Makoto Nitta

Book ID: 104216697
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 255 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80591-2

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✦ Synopsis

2-Halocycloheptadienone enolates, 7

which were generated by the reaction of 2-halotropones with hydride, Grignard, and organolithium reagents, reacted with cationic electrophiles including tropylium ion to give 2-substituted tropone derivatives.

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