Synthesis of 1-amino-1,2,5-trideoxy-2,5-
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Tanja M. Wrodnigg; Arnold E. Stütz; Steven G. Withers
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Article
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1997
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Elsevier Science
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French
⚖ 179 KB
By an Amadori rearrangement of easily available 5-azido-5-deoxy-D-glucofuranose with dibenzylamine and subsequent catalytic hydrogenation of the resulting 5-azido-l-dibenzylamino-l,5dideoxy-D-fructopyranose, the new l-amino-l,2,5-trideoxy-2,5-ilnino-D-mannitol was obtained in only two steps and exce