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Synthesis of tetrasubstituted pyridazinesviacascade reactions of diazocarbonyl compounds with pyridinium ylides

✍ Scribed by Yu. V. Tomilov; D. N. Platonov; D. V. Dorokhov; A. A. Zhalnina

Book ID
106520887
Publisher
Springer
Year
2008
Tongue
English
Weight
331 KB
Volume
57
Category
Article
ISSN
1573-9171

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## Abstract The reaction of Rh^II^–oxocarbenoids derived from acyclic diazocarbonyl compounds with phthalimide and succinimide proceeds chemoselectively at the oxygen atom of the imidic carbonyl group, giving rise to the intermediate formation of carbonyl ylides. Intramolecular stabilization of the