RhII-Catalyzed Reactions of Diazocarbony
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Vsevolod V. Nikolaev; Heinz Heimgartner; Anthony Linden; Ivan S. Krylov; Valerij
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Article
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2006
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John Wiley and Sons
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English
⚖ 189 KB
## Abstract The reaction of Rh^II^–oxocarbenoids derived from acyclic diazocarbonyl compounds with phthalimide and succinimide proceeds chemoselectively at the oxygen atom of the imidic carbonyl group, giving rise to the intermediate formation of carbonyl ylides. Intramolecular stabilization of the