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Synthesis and reactions of α-metallated diazocarbonyl compounds

✍ Scribed by O. A. Kruglaya; I. B. Fedot'eva; B. V. Fedot'ev; N. S. Vyazankin; I. D. Kalikhman

Book ID
112488465
Publisher
Springer
Year
1975
Tongue
English
Weight
222 KB
Volume
24
Category
Article
ISSN
1573-9171

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✍ Rolf Huisgen; Hans-Ulrich Reissig; Helmut Huber; Sabine Voss 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 246 KB

2,5-Dimethyl-l -pyrroIidinocyclopentene produces with methyl diazoacetate and diazoketones Summary 2-pyrazolines OS cycloadducts whereas with dimethyl diazomalonote an CIZO coupling equilibrium is established. The rate constants of these two reactions respond differently to solvent polarity. N-Cyclo