𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis of sulfido(pentamethylcyclopentadienyl)tantalum complex (C5Me5)Ta(S)32- and the structure of a hexagonal-prismatic Ta2Li4S6 core

✍ Scribed by Tatsumi, Kazuyuki; Inoue, Yoshihisa; Nakamura, Akira; Cramer, Roger E.; VanDoorne, William; Gilje, John W.

Book ID
127280859
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
295 KB
Volume
111
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis, Structural Characterisation a
Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB 👁 1 views

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3