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Metallocene sulfide chemistry of niobium and tantalum: new insights into the formation of niobium-polysulfido complexes and synthesis, structure, and reactivity of Cp2'Ta(.eta.2-S2)H (Cp' = tert-BuC5H4)

โœ Scribed by Bach, Hans Juergen; Brunner, Henri; Wachter, Joachim; Kubicki, Marek M.; Leblanc, Jean Claude; Moise, Claude; Volpato, Florence; Nuber, Bernd; Ziegler, Manfred L.


Book ID
127194899
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
630 KB
Volume
11
Category
Article
ISSN
0276-7333

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The reaction of [Cp\*MCl 4 ] (M ฯญ Nb, Ta; Cp\* ฯญ C 5 Me 5 ) with PH 2 R in toluene at room temperature gives the primary phosphine complexes [Cp\*MCl 4 (PH 2 R)] [Cp\* ฯญ C 5 Me 5 ; M ฯญ Nb: R ฯญ Bu t (1a), Ad (2a), Cy (3a), Ph (4a), 2,4,6-Me 3 C 6 H 2 (Mes) (5a); M ฯญ Ta: R ฯญ Bu t (1b), Ad (2b), Cy (3b

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