✦ LIBER ✦

Synthesis of stereospecifically labeled carbohydrates II1: preparation of (3S)- and (3R)-[3-2H1]abequose

✍ Scribed by Theresa M. Weigel; Hung-wen Liu

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 240 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)80459-1

No coin nor oath required. For personal study only.

✦ Synopsis

preparation of methyl 3,6-dideoxy-D-xylo-hexapyranoside (methyl abequoside) having deuterium stereospecifically labeled at the 3s (1) and 3R (2) position, respectively, via three different routes is described.

The 3.6~didwxyhexoses are found in the lipopolysaccharides of a number of gram-negative bacteria, where they have been shown to be the dominant immunological antigenic determinants.2 As a part of our

📜 SIMILAR VOLUMES

Synthesis of stereospecifically labeled

Synthesis of stereospecifically labeled carbohydrates: Preparation of (3S)− and (3R)-[3-2H1]ascarylose

✍ Oksoo Han; Hung-wen Liu 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 213 KB

Synthesis of [3H2]-(R,R)-1,2-diaminocycl

Synthesis of [3H2]-(R,R)-1,2-diaminocyclohexaneoxalatoplatinum(II), [3H2]-Oxaliplatin

✍ Alain Burgos; George J. Ellames 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 French ⚖ 234 KB 👁 1 views

The stereospecific synthesis of (2S,3R)

The stereospecific synthesis of (2S,3R) 3-carboxyproline and (2S,3R) 3-aminoproline

✍ Jack E. Baldwin; Robert M. Adlington; David W. Gollins; Christopher R.A. Godfrey 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 632 KB

Synthesis of (2S,2′R,3′R)-2-(1′-[3H],2′,

Synthesis of (2S,2′R,3′R)-2-(1′-[3H],2′,3′-dicarboxylcyclopropyl)-glycine ([3H]-DCG-IV)

✍ Jürgen Wichmann; Philipp Huguenin; Geo Adam 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 French ⚖ 248 KB 👁 1 views

Asymmetric synthesis of [C-1-3H]-labelle

Asymmetric synthesis of [C-1-3H]-labelled (+)-trans [1R,3R]-chrysanthemic acid

✍ Gerald Pattenden; Richard Storer 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 French ⚖ 212 KB

## Abstract A facile asymmetric synthesis of [C‐1‐^3^H]‐labelled (+)‐trans[1R,3R]‐chrysanthemic acid, required for biosynthetic studies is described. The tritium labelled acid is prepared from the corresponding (−)‐cis[1S,3R]‐ester by selective epimerisation of the C‐1 centre in the latter, in the

Experiments with stereospecifically-labe

Experiments with stereospecifically-labelled amino acids: Convenient synthesis of (2SR, 3SR)-[3-2H1]phenylalanine

✍ U. Müller; D.H.G. Crout 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 264 KB