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Synthesis of some thioglycidyl esters of monobasic carboxylic acids

✍ Scribed by M. A. Allakhverdiev; N. A. Akrepov; V. M. Farzaliev; G. A. Zeinalova; Kh. M. Bagirova

Publisher
Springer US
Year
1989
Tongue
English
Weight
218 KB
Volume
25
Category
Article
ISSN
0009-3122

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✦ Synopsis

Thioglycidyl esters of monobasic carboxylic acids were synthesized by thioepoxidation of glycidyl esters of thiourea.

Despite the fact that data on the methods of synthesis and on the properties of thiirane compounds have been correlated and systematized in a monograph [i], the amount of data in the literature regarding thioglycidyl esters of monobasic carboxylic acids is small. Acetic acid thioglyeidyl ester was obtained for the first time in [2] by the reaction of potassium acetate with thioepichlorohydrin.

This method was then perfected [3]. Thioglycidyl esters of acetic, methacrylic, and benzoic acids were obtained by Arbuzov and coworkers [4,5] by thioepoxidation of the corresponding oxiranes with thiourea.

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