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Synthesis of Six-Membered Functionalized Carbocyclic Compounds by One-Pot Reaction of Hydroquinone Derivatives and Dienes

โœ Scribed by Cai, Guang-Rong; Guan, Zhi; He, Yan-Hong

Book ID
115465958
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
345 KB
Volume
41
Category
Article
ISSN
0039-7911

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The Michael addition reactions of fl-nitrostyrenes 1 with 4-pentene-l-magnesium bromide 2a or 3-butene-l-magnesium bromide 2b generated nitronates 3 or 4. Medium to high yields of isoxazolidine derivatives 9 and 10 were obtained when nitronates 3 or 4 were treated with ethyl chloroformate and cataly