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Generation of Allylic Indium by Hydroindation of 1,3-Dienes and One-Pot Reaction with Carbonyl Compounds

โœ Scribed by Hayashi, Naoki; Honda, Hiroyuki; Yasuda, Makoto; Shibata, Ikuya; Baba, Akio


Book ID
126951248
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
67 KB
Volume
8
Category
Article
ISSN
1523-7060

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Indium-Mediated Reaction of 1,3-Dichloro-and 1,3-Dibromopropenes with Carbonyl Compounds. Generation of Novel 3,3-Diindiopropene. -Aromatic aldehydes such as benzaldehyde (I) undergo an indium-mediated reaction with 1,3-dichloropropene (II) to give the syn-chlorohydrin ( III) predominantly. 1,3-Dib