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ChemInform Abstract: One-Pot Synthesis of Five- or Six-Membered Carbocycles Through Intramolecular Cycloadditions by the Use of Ethyl Chloroformate.

✍ Scribed by Ju-Tsung Liu; Wen-Wei Lin; Jeong-Jiunn Jang; Jing-Yuan Liu; Ming-Chung Yan; Chihua Hung; Kuo-Hsi Kao; Yeh Wang; Ching-Fa Yao


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
30
Category
Article
ISSN
0931-7597

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✍ I. N. N. NAMBOOTHIRI; A. HASSNER; H. E. GOTTLIEB 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

Strategy for the Construction of Functionalized Five-and Six-Membered Carbocycles. -Conjugate addition of the Grignard reagents (II) and (IV) to the nitro olefins (I) leads to the intermediate formation of nitronates, which are trapped as silyl nitronates and subsequently cyclized by intramolecular