Synthesis of silver(I) complexes with carbonyl-stabilized phosphorus ylides: crystal structures of two [Ag{;CH(PPh3)C(O)R};2]+ derivatives
β Scribed by J. Vicente; M.T. Chicote; J. Fernandez-Baeza; J. Martin; I. Saura-Llamas; J. Turpin; Peter G. Jones
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 762 KB
- Volume
- 331
- Category
- Article
- ISSN
- 0022-328X
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Silver(1) complexes I Bis(diphenylphosphany1)-o-carborane I o-Carborane Silver(1) perchlorate or nitrate react readily with bis(di-phenylphosphany1)-o-carborane to give the complexes [AgX((PPh2)2C2BloHlo)1 [X = C104 (l), NO3 (2)]. The perchlorate ligand is weakly bound to the silver atom and thus ca
## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Singleβcrystal Xβray analyses indicate that the CB~11~I~5~Br~6~^2β^ dianion has a signi