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Transition metal-cyanocarbon chemistry: VII. Reactions of mono- and di-cyanoacetylenes with tricarbonylcyclopentadienylmethylthiolatotungsten(II). Formation of phosphorus ylide complex [(C5H5)(CO)2W(CH(P(C6H5)3)C(CN)SCH3)]. Crystal structure of [(C5H5)(CO)2(P(C6H5)3)-W(C(O)C(CN)CHSCH3)·CH2Cl2]

✍ Scribed by M.M. Kubicki; R. Kergoat; H. Scordia; L.C.Gomes de Lima; J.E. Guerchais; P. L'Haridon


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
599 KB
Volume
340
Category
Article
ISSN
0022-328X

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Molecular Structure of [η-C5H5(CO)2ReC(C
✍ Dr. Fritz R. Kreissl; Dipl.-Chem. Peter Friedrich 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB 👁 1 views

The crystallographic dataC3] and the molecular dimensions of ( 4 ) and ( ) are almost identical. We thus have one of those rare cases in which analyses and spectraL4] are more significant in identifying the compounds than structure determination. The most important structural characteristic of ( 4 )