Gold(I) and Silver(I) Complexes with Methanide Ligands [C{PPh2(X)}3]– (X = O, S). Crystal Structures of [M{C(PPh2(X))3}(PPh3)] (M Au, X O; M Ag, X S)
✍ Scribed by Gimeno, M. Concepción ;Jones, Peter G. ;Laguna, Antonio ;Villacampa, M. Dolores
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1996
- Tongue
- English
- Weight
- 443 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0009-2940
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Two new 1,2,3,5-dithiadiazoles, [4-(4Ј-C 5 H 4 N)CN 2 S 2 ] (L 1 ) and [4-(3Ј-C 5 H 4 N)CN 2 S 2 ] (L 2 ), with different pyridyl groups at the 4-position were prepared. As Lewis bases, the dithiadiazoles reacted with Lewis acids via their pyridyl groups to form acid-base adducts with retention of t