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Synthesis of rod-shaped compounds: bis(7,7′-heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecanylidene) derivatives

✍ Scribed by Tahsin J. Chow; Yung-Son Hon; Chong-Yow Chen; Min-Shiang Huang

Book ID
104262397
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
179 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

6

13 II 59 1014

The rod-shaped hydrocarbon molecules 1 and 2 are synthesized from heptacyclo[6.6.0.02' .03' .04' .0, .0 ' ]tetradecane (HCTD) derivatives according to Barton's procedure, where the structures of 1 and the corresponding diketone of 2 belong to D2h and D~ symmetries, respectively.

📜 SIMILAR VOLUMES

Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.0
Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecane: a new type of spacer for mediating electron transfer processes
✍ Nan-Rong Chiou; Tahsin J Chow; Chong-Yow Chen; Ming-Ann Hsu; Hong-Chuan Chen 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 76 KB

A series of derivatives of the titled compound with donor and acceptor substituents were prepared. Efficient fluorescence quenching was observed for the molecules in which donor and acceptor p-chromophores are coplanar. Charge recombination of the radical ion pairs resulted in broad charge transfer

Photoinduced electron transfer reaction
Photoinduced electron transfer reaction tuned by donor–acceptor pairs via the rigid, linear spacer heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecane
✍ Tahsin J. Chow; Nan-Rong Chiu; Hong-Chuan Chen; Chong-Yow Chen; Wei-Shan Yu; Yi- 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 333 KB

Photoinduced electron transfer reaction tuned by donor -acceptor pairs via the rigid, linear spacer heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]tetradecane