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ChemInform Abstract: Heptacyclo [6.6.0.02,6.03,13.04,11.0 5,9.010,14]tetradecane: A New Type of Spacer for Mediating Electron Transfer Processes.

✍ Scribed by Nan-Rong Chiou; Tahsin J. Chow; Chong-Yow Chen; Ming-Ann Hsu; Hong-Chuan Chen

Book ID
101902982
Publisher
John Wiley and Sons
Year
2001
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.0
Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecane: a new type of spacer for mediating electron transfer processes
✍ Nan-Rong Chiou; Tahsin J Chow; Chong-Yow Chen; Ming-Ann Hsu; Hong-Chuan Chen πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 76 KB

A series of derivatives of the titled compound with donor and acceptor substituents were prepared. Efficient fluorescence quenching was observed for the molecules in which donor and acceptor p-chromophores are coplanar. Charge recombination of the radical ion pairs resulted in broad charge transfer

Photoinduced electron transfer reaction
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Photoinduced electron transfer reaction tuned by donor -acceptor pairs via the rigid, linear spacer heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]tetradecane