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Photoinduced electron transfer reaction tuned by donor–acceptor pairs via the rigid, linear spacer heptacyclo[6.6.0.02,6.03,13.04,11.05,9.010,14]tetradecane

✍ Scribed by Tahsin J. Chow; Nan-Rong Chiu; Hong-Chuan Chen; Chong-Yow Chen; Wei-Shan Yu; Yi-Ming Cheng; Chung-Chih Cheng; Chen-Pin Chang; Pi-Tai Chou


Book ID
104205518
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
333 KB
Volume
59
Category
Article
ISSN
0040-4020

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✦ Synopsis


Photoinduced electron transfer reaction tuned by donor -acceptor pairs via the rigid, linear spacer heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]tetradecane


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Heptacyclo[6.6.0.02,6.03,13.04,11.05,9.0
✍ Nan-Rong Chiou; Tahsin J Chow; Chong-Yow Chen; Ming-Ann Hsu; Hong-Chuan Chen 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 76 KB

A series of derivatives of the titled compound with donor and acceptor substituents were prepared. Efficient fluorescence quenching was observed for the molecules in which donor and acceptor p-chromophores are coplanar. Charge recombination of the radical ion pairs resulted in broad charge transfer