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Synthesis of (R)- and (S)-isomers of 1-methylspermidine

✍ Scribed by Nikolay A. Grigorenko; Jouko Vepsalainen; Aki Jarvinen; Tuomo Keinanen; Leena Alhonen; Juhani Janne; Alex R. Khomutov

Book ID
111730589
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
91 KB
Volume
15
Category
Article
ISSN
0959-9436

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## Abstract (βˆ’)‐Bicolorin [(1__S__,2__R__,5__R__)‐(βˆ’)‐2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1)], the male‐produced pheromone of __Taphrorychus bicolor__, and its (1__R__,2__R__,5__S__) isomer 2 were synthesized by starting from (__S__)‐limonene oxide (3), employing osmium tetroxide ca