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Synthesis of quinoxalinones by the reaction of o-phenylenediamines with dimethyl acetylenedicarboxylate

โœ Scribed by Suschitzky, Hans; Wakefield, Basil J.; Whittaker, Roger A.

Book ID
120038700
Publisher
Royal Society of Chemistry
Year
1975
Weight
461 KB
Volume
5
Category
Article
ISSN
1472-7781

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The reaction of cyclohexyl isocyanide an
The reaction of cyclohexyl isocyanide and dimethyl acetylenedicarboxylate with o- and p-quinones: a novel synthesis of iminolactones
โœ Vijay Nair; A.U Vinod; J.Somarajan Nair; A.R Sreekanth; Nigam P Rath ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 178 KB

The 1:1 intermediate generated by the addition of cyclohexyl isocyanide to dimethyl acetylenedicarboxylate is trapped by quinones to yield iminolactones in good yields.