The cycloaddition reaction of 2,6-dimethylphenylisonitrile with dimethyl acetylenedicarboxylate
β Scribed by Yoshio Suzuki; Naruyoshi Obata; Takeo Takizawa
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- French
- Weight
- 214 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The [2+2] cycloaddition reaction of dimethyl acetylenedicarboxylate (DMAD) and the P O moiety of cyclic P-(2,4,6-triisopropylphenyl) phosphine oxides giving an entry to oxaphosphetes is of general value and extended to cyclic and alicyclic phosphine oxides with different trialkylphenyl substituents
Reaction of benzimidazole-2(2@-thione 2 with dimethyl acetylenedicarboxylate (DMAD) has been reported by Grinblat and Postovskii to give the thiazolo[3,2-albenzimidazole 2.' On mechanistic grounds, however, condensation of i with DMAD can give rise to one or more of at least four products ,2, 2, 4~