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The cycloaddition reaction of 2,6-dimethylphenylisonitrile with dimethyl acetylenedicarboxylate

✍ Scribed by Yoshio Suzuki; Naruyoshi Obata; Takeo Takizawa


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
214 KB
Volume
11
Category
Article
ISSN
0040-4039

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The [2+2] cycloaddition reaction of dimethyl acetylenedicarboxylate (DMAD) and the P O moiety of cyclic P-(2,4,6-triisopropylphenyl) phosphine oxides giving an entry to oxaphosphetes is of general value and extended to cyclic and alicyclic phosphine oxides with different trialkylphenyl substituents

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Reaction of benzimidazole-2(2@-thione 2 with dimethyl acetylenedicarboxylate (DMAD) has been reported by Grinblat and Postovskii to give the thiazolo[3,2-albenzimidazole 2.' On mechanistic grounds, however, condensation of i with DMAD can give rise to one or more of at least four products ,2, 2, 4~