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The Reaction of iminosulfuranes with dimethyl acetylenedicarboxylate

✍ Scribed by Y. Hayashi; Y. Iwagami; A. Kadoi; T. Shono; Daniel Swern

Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
206 KB
Volume
15
Category
Article
ISSN
0040-4039

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The reaction of cyano-carbalkoxy-pyridin
The reaction of cyano-carbalkoxy-pyridinium-methylids with dimethyl acetylenedicarboxylate
✍ C. Leonte; I. ZugrΔƒvescu πŸ“‚ Article πŸ“… 1972 πŸ› Elsevier Science 🌐 French βš– 226 KB

The heterocyclic nitrogen ylids react as 1.3 dipoles with acetylenic dipolarophilea, leading, via a hypothetic&L dibydroaromatio cycloadduot, to axowatic bicyclic derivatives, as follows (1,2>: On the other hand, in the case of heterocyclic dioyenomethylids (R P B' = CR), the intenuediary cycloaddu