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Synthesis of Pyrrolyl-, Indolyl-, and Carbazolylphosphanes and Their Catalytic Application as Ligands in the Hydroformylation of 2-Pentene

✍ Scribed by Ralf Jackstell; Holger Klein; Matthias Beller; Klaus-Diether Wiese; Dirk Röttger

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 278 KB
Volume: 2001
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200110)2001:20<3871::aid-ejoc3871>3.0.co;2-v

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## Abstract The synthesis of calix[4]arene‐based phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)‐ catalyzed hydroformylation of 1‐octene. Depending on the reaction conditions, yields up to 99% and __n/iso__‐selectivities between 0.7 and 2.6 h