Synthesis of Group 9 Metal-Olefin Comple
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Nico Weding; Ralf Jackstell; Haijun Jiao; Anke Spannenberg; Marko Hapke
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Article
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2011
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John Wiley and Sons
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English
β 338 KB
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The preparation and catalytic evaluation of the three group 9 (cyclopentadienyl)metal(trimethylvinylsilane) complexes of the type C 5 H 5 M(H 2 C= CHSiMe 3 ) 2 (M = cobalt, rhodium and iridium) are reported. The complexes were investigated in [2 + 2 + 2] cycloaddition as well as in hydrogenation, hy