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Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes

โœ Scribed by Tang-Zhi Zhang; Li-Xin Dai; Xue-Long Hou


Book ID
108284177
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
733 KB
Volume
18
Category
Article
ISSN
0957-4166

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๐Ÿ“œ SIMILAR VOLUMES


Novel planar chiral P,N-[2.2]paracycloph
โœ Xun-Wei Wu; Ke Yuan; Wei Sun; Ming-Jie Zhang; Xue-Long Hou ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 251 KB

A series of planar chiral P,N-[2.2]paracyclophane ligands were synthesized and applied in enantioselective palladiumcatalyzed allylic alkylation, in which the central chirality of [2.2]paracyclophane is the dominant stereocontrol element. The effect of the substituents attached to the phosphorus ato